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Chemical characteristics of fine particulate matter emitted from commercial cooking

Bing PEI,Hongyang CUI,Huan LIU,Naiqiang YAN

《环境科学与工程前沿（英文）》 2016年第10卷第3期页码 559-568 doi: 10.1007/s11783-016-0829-y

摘要： The chemical characteristics of fine particulate matter (PM ) emitted from commercial cooking were explored in this study. Three typical commercial restaurants in Shanghai, i.e., a Shanghai-style one (SHS), a Sichuan-style one (SCS) and an Italian-style one (ITS), were selected to conduct PM sampling. Particulate organic matter (POM) was found to be the predominant contributor to cooking-related PM mass in all the tested restaurants, with a proportion of 69.1% to 77.1%. Specifically, 80 trace organic compounds were identified and quantified by gas chromatography/mass spectrometry (GC/MS), which accounted for 3.8%–6.5% of the total PM mass. Among the quantified organic compounds, unsaturated fatty acids had the highest concentration, followed by saturated fatty acids. Comparatively, the impacts of other kinds of organic compounds were much smaller. Oleic acid was the most abundant single species in both SCS and ITS. However, in the case of SHS, linoleic acid was the richest one. ITS produced a much larger mass fraction of most organic species in POM than the two Chinese cooking styles except for monosaccharide anhydrides and sterols. The results of this study could be utilized to explore the contribution of cooking emissions to PM pollution and to develop the emission inventory of PM from cooking, which could then help the policy-makers design efficient treatment measures and control strategies on cooking emissions in the future.

关键词： commercial cooking PM_2.5 chemical characteristics organic matter

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Numerical investigation of the chemical and electrochemical characteristics of planar solid oxide fuel

Yuzhang WANG, Shilie WENG, Yiwu WENG

《能源前沿（英文）》 2011年第5卷第2期页码 195-206 doi: 10.1007/s11708-011-0148-8

摘要： A fully three-dimensional mathematical model of a planar solid oxide fuel cell (SOFC) with complete direct internal steam reforming was constructed to investigate the chemical and electrochemical characteristics of the porous-electrode-supported (PES)-SOFC developed by the Central Research Institute of Electric Power Industry of Japan. The effective kinetic models developed over the Ni/YSZ anode takes into account the heat transfer and species diffusion limitations in this porous anode. The models were used to simulate the methane steam reforming processes at the co- and counter-flow patterns. The results show that the flow patterns of gas and air have certain effects on cell performance. The cell at the counter-flow has a higher output voltage and output power density at the same operating conditions. At the counter-flow, however, a high hotspot temperature is observed in the anode with a non-fixed position, even when the air inlet flow rate is increased. This is disadvantageous to the cell. Both cell voltage and power density decrease with increased air flow rate.

关键词： planar solid oxide fuel cell (SOFC) direct internal reforming chemical reaction methane electrochemical

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Inverse uncertainty characteristics of pollution source identification for river chemical spill incidents

Jiping Jiang, Feng Han, Yi Zheng, Nannan Wang, Yixing Yuan

《环境科学与工程前沿（英文）》 2018年第12卷第5期 doi: 10.1007/s11783-018-1081-4

摘要：

Uncertainty rules of pollution source inversion are revealed by stochastic analysis

A release load is most easily inversed and source locations own largest uncertainty

Instantaneous spill assumption has much less uncertainty than continuous spill

The estimated release locations and times negatively deviate from real values

The new findings improve monitoring network design and emergency response to spills

关键词： River chemical spills Emergency response Pollution source inversion Inverse uncertainty analysis Regional Sensitivity Analysis method (RSA) Monte Carlo analysis toolbox (MCAT)

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The influence of chlorinated aromatics' structure on their adsorption characteristics on activated carbonto tackle chemical spills in drinking water source

Pengfei LIN,Yuan ZHANG,Xiaojian ZHANG,Chao CHEN,Yuefeng XIE,Irwin H SUFFET

《环境科学与工程前沿（英文）》 2015年第9卷第1期页码 138-146 doi: 10.1007/s11783-014-0725-2

摘要： This study focused on evaluating the efficiency of powdered activated carbon (PAC) adsorption process and tackling chlorobenzenes and chlorophenols spill in drinking water source. The adsorption kinetics and PAC’s capacities for five chlorobenzenes and three chlorophenols at drinking water contamination levels were studied in order to determine the influence of different functional groups on the adsorption behavior. The results showed that PAC adsorption could be used as an effective emergency drinking water treatment process to remove these compounds. The adsorption kinetics took 30 min to achieve nearly equilibrium and could be described by both pseudo first-order and pseudo second-order models. A mathematic relationship was developed between the pseudo first-order adsorption rate constant, k , and the solutes’ properties including lg , polarizability and molecular weight. The Freundlich isotherm equation could well describe the adsorption equilibrium behaviors of chlorinated aromatics with from 0.920 to 0.999. The H-bond donor/acceptor group, hydrophobicity, solubility and molecular volume were identified as important solute properties that affect the PAC adsorption capacity. These results could assist water professionals in removing chlorinated aromatics during emergency drinking water treatment.

关键词： chlorinated aromatics adsorption powdered activated carbon kinetics equilibrium

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Characteristics of chemical components in PM

Jianwu SHI,Xiang DING,Yue ZHOU,Ran YOU,Lu HUANG,Jiming HAO,Feng XIANG,Jian YANG,Ze SHI,Xinyu HAN,Ping NING

《环境科学与工程前沿（英文）》 2016年第10卷第5期 doi: 10.1007/s11783-016-0841-2

摘要： The mass concentrations of PM were studied at a plateau city. Seasonal and spatial variation of chemical components in PM were analyzed. Primary emissions were the main contributors of PM . A sampling campaign including summer, autumn and winter of 2014 and spring of 2015 was accomplished to obtain the characteristic of chemical components in PM at three sites of Kunming, a plateau city in South-west China. Nine kinds of water-soluble inorganic ions (WSI), organic and element carbon (OC and EC) in PM were analyzed by ion chromatography and thermal optical reflectance method, respectively. Results showed that the average concentrations of total WSI, OC and EC were 22.85±10.95 μg·m , 17.83±9.57 μg·m and 5.11±4.29 μg·m , respectively. They totally accounted for 53.0% of PM . Secondary organic and inorganic aerosols (SOA and SIA) were also assessed by the minimum ratio of OC/EC, nitrogen and sulfur oxidation ratios. The annual average concentrations of SOA and SIA totally accounted for 28.3% of the PM concentration. The low proportion suggested the primary emission was the main source of PM in Kunming. However, secondary pollution in the plateau city should also not be ignorable, due to the appropriate temperature and strong solar radiation, which can promote the atmospheric photochemical reactions.

关键词： PM_2.5 Plateau city Organic carbon Element carbon Inorganic ions Secondary components

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Special issue on “Green chemical process and intensification”

《化学科学与工程前沿（英文）》 2022年第16卷第11期页码 1533-1535 doi: 10.1007/s11705-022-2263-y

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Special Issue for the Future Chemical Engineering Scholars of Global Chinese Chemical Engineering Symposium

《化学科学与工程前沿（英文）》 2022年第16卷第6期页码 775-776 doi: 10.1007/s11705-022-2172-0

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Insight of chemical environmental risk and its management from the vinyl chloride accident

《环境科学与工程前沿（英文）》 2023年第17卷第4期 doi: 10.1007/s11783-023-1652-x

摘要： The combustion of vinyl chloride (VC) after the train derailment accident in Ohio, USA in February, 2023 has caused widespread concern around the world. This paper tried to analyze several issues concerning the accident, including the appropriateness of the VC combustion in the emergency response in this accident, the meanings of so-called “controlled combustion”, the potential environmental risks caused by VC and combustion by-products, and follow-up work. In our view, this accident had surely caused environmental and health risks to some extent. Hence, a comprehensive environmental risk assessment is necessary, and then the site with risk should be comprehensively remediated, hazardous waste should be harmlessly treated as soon as possible. Finally, this accident suggests that further efforts should be taken to bridge the gap between chemical safety management and their environmental risk management.

关键词： Vinyl chloride Combustion Chemical safety management Environmental risk Emerging contaminants

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Effects of sulfur on variations in the chemical speciation of heavy metals from fly ash glass

《环境科学与工程前沿（英文）》 2023年第17卷第10期 doi: 10.1007/s11783-023-1728-7

摘要：

● A higher sulfur content reduced the curing rate of Cr in glass.

关键词： Dechlorinated fly ash SO₃ Heavy metal Chemical speciation Glass solidification

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我国林产化学工业发展的新动向

宋湛谦

《中国工程科学》 2001年第3卷第2期页码 1-6

摘要：

林产化学工业是将可再生的森林资源经过化学加工生产出各种有用的产品。它是森林资源高效可持续利用的一个重要组成部分。文章介绍我国林产化学工业的现状，并指出今后发展方向，即加强创新研究，开发深加工产品；推进林产化工企业向大型化发展；发展木材制浆造纸和开发木质能源。

关键词：林产化学工业森林资源化学加工

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Bioinspired and biomimetic membranes for water purification and chemical separation: A review

《环境科学与工程前沿（英文）》 2021年第15卷第6期 doi: 10.1007/s11783-021-1412-8

摘要：

•The history of biological and artificial water channels is reviewed.

关键词： Aquaporins Artificial water channels Biomimetic membranes Chemical separation and water purification

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Chemical transdifferentiation: closer to regenerative medicine

null

《医学前沿（英文）》 2016年第10卷第2期页码 152-165 doi: 10.1007/s11684-016-0445-z

摘要：

Cell transdifferentiation, which directly switches one type of differentiated cells into another cell type, is more advantageous than cell reprogramming to generate pluripotent cells and differentiate them into functional cells. This process is crucial in regenerative medicine. However, the cell-converting strategies, which mainly depend on the virus-mediated expression of exogenous genes, have clinical safety concerns. Small molecules with compelling advantages are a potential alternative in manipulating cell fate conversion. In this review, we briefly retrospect the nature of cell transdifferentiation and summarize the current developments in the research of small molecules in promoting cell conversion. Particularly, we focus on the complete chemical compound-induced cell transdifferentiation, which is closer to the clinical translation in cell therapy. Despite these achievements, the mechanisms underpinning chemical transdifferentiation remain largely unknown. More importantly, identifying drugs that induce resident cell conversion in vivo to repair damaged tissue remains to be the end-goal in current regenerative medicine.

关键词： cell therapy cell transdifferentiation chemical compounds small molecules tissue regeneration

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Computational design of structured chemical products

Faheem Mushtaq, Xiang Zhang, Ka Y. Fung, Ka M. Ng

《化学科学与工程前沿（英文）》 2021年第15卷第5期页码 1033-1049 doi: 10.1007/s11705-020-2002-1

摘要： In chemical product design, the aim is to formulate a product with desired performance. Ingredients and internal product structure are two key drivers of product performance with direct impact on the mechanical, electrical, and thermal properties. Thus, there is a keen interest in elucidating the dependence of product performance on ingredients, structure, and the manufacturing process to form the structure. Design of product structure, particularly microstructure, is an intrinsically complex problem that involves different phases of different physicochemical properties, mass fraction, morphology, size distribution, and interconnectivity. Recently, computational methods have emerged that assist systematic microstructure quantification and prediction. The objective of this paper is to review these computational methods and to show how these methods as well as other developments in product design can work seamlessly in a proposed performance, ingredients, structure, and manufacturing process framework for the design of structured chemical products. It begins with the desired target properties and key ingredients. This is followed by computation for microstructure and then selection of processing steps to realize this microstructure. The framework is illustrated with the design of nanodielectric and die attach adhesive products.

关键词： product design performance ingredients structure manufacturing process framework structured chemical products microstructure design

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Hexachlorobutadiene emissions from typical chemical plants

Minxiang Wang, Lili Yang, Xiaoyun Liu, Zheng Wang, Guorui Liu, Minghui Zheng

《环境科学与工程前沿（英文）》 2021年第15卷第4期 doi: 10.1007/s11783-020-1352-8

摘要： Abstract • Unintentional HCBD production in typical chemical plants was investigated. • The highest HCBD concentrations were found in the bottom residue. • Tri/tetrachloroethylene production processes were important HCBD sources. Hexachlorobutadiene (HCBD) was classed as a persistent organic pollutant under the Stockholm Convention in 2015. HCBD is mainly an unintentionally produced by-product of chlorinated hydrocarbon (e.g., trichloroethylene and tetrachloroethylene) synthesis. Few studies of HCBD formation during chemical production processes have been performed, so HCBD emissions from these potentially important sources are not understood. In this study, HCBD concentrations in raw materials, intermediate products, products, and bottom residues from chemical plants producing chlorobenzene, trichloroethylene, and tetrachloroethylene were determined. The results indicated that HCBD is unintentionally produced at much higher concentrations in trichloroethylene and tetrachloroethylene plants than chlorobenzene plants. The sum of the HCBD concentrations in the samples from all of the trichloroethylene and tetrachloroethylene production stages in plant PC was 247000 mg/mL, about three orders of magnitude higher than the concentrations in the tetrachloroethylene production samples (plant PB) and about six orders of magnitude higher than the concentrations in the chlorobenzene production samples (plant PA). The HCBD concentrations were highest in bottom residues from all of the plants. The concentrations in the bottom residue samples contributed 24%–99% of the total HCBD formed in the chemical production plants. The bottom residue, being hazardous waste, could be disposed of by incineration. The HCBD concentrations were much higher in intermediate products than raw materials, indicating that HCBD formed during production of the intended chemicals. The results indicate the concentrations of HCBD unintentionally produced in typical chemical plants and will be useful in developing protocols for controlling HCBD emissions to meet the Stockholm Convention requirements.

关键词： Hexachlorobutadiene Chemical plant Chlorobenzene Trichloroethylene Tetrachloroethylene

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Opportunities and challenges for a Golden Age of chemical engineering

Phillip R. WESTMORELAND

《化学科学与工程前沿（英文）》 2014年第8卷第1期页码 1-7 doi: 10.1007/s11705-014-1416-z

摘要： Chemical engineering is entering a new Golden Age of practice, thought, and impact, accompanied by great new opportunities and challenges. Five aspects mark this development: a new abundance of hydrocarbons; the evolution of biology into a molecular science; the ubiquity of powerful computational tools; the trend in manufacturing to be more process-oriented; and the systems approach that is part of ChE education from its first stages. There are important technical challenges, including technology creation and environmental impact, but just as important are new appreciation for and attention to challenges that require societal dialogues about complexity, uncertainty, and evolving and sometimes contradictory requirements. Crucial to all these impacts is enhancing the identity of what the profession is. That must be based on recognizing that the core of chemical engineering is applying molecular sciences to create value and advance the quality of life.

关键词： hydrocarbons biotechnology computation cyberinfrastructure manufacturing environmental

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标题作者时间类型操作

Chemical characteristics of fine particulate matter emitted from commercial cooking

Bing PEI,Hongyang CUI,Huan LIU,Naiqiang YAN

期刊论文

Numerical investigation of the chemical and electrochemical characteristics of planar solid oxide fuel

Yuzhang WANG, Shilie WENG, Yiwu WENG

期刊论文

Inverse uncertainty characteristics of pollution source identification for river chemical spill incidents

Jiping Jiang, Feng Han, Yi Zheng, Nannan Wang, Yixing Yuan

期刊论文

The influence of chlorinated aromatics' structure on their adsorption characteristics on activated carbonto tackle chemical spills in drinking water source

Pengfei LIN,Yuan ZHANG,Xiaojian ZHANG,Chao CHEN,Yuefeng XIE,Irwin H SUFFET

期刊论文

Characteristics of chemical components in PM

Jianwu SHI,Xiang DING,Yue ZHOU,Ran YOU,Lu HUANG,Jiming HAO,Feng XIANG,Jian YANG,Ze SHI,Xinyu HAN,Ping NING

期刊论文

Special issue on “Green chemical process and intensification”

期刊论文

Special Issue for the Future Chemical Engineering Scholars of Global Chinese Chemical Engineering Symposium

期刊论文

Insight of chemical environmental risk and its management from the vinyl chloride accident

期刊论文

Effects of sulfur on variations in the chemical speciation of heavy metals from fly ash glass